Deuterated polymer gels for measuring anisotropic NMR parameters with strongly reduced artefacts

ChemComm, 2008, 10.1039/b812905c, 5722-4 published on 06.10.2008
ChemComm, online article
Perdeuterated poly(styrene) is introduced as an almost artefactfree and arbitrarily scalable alignment medium for measuring residual dipolar couplings and other anisotropic NMR parameters; the spectral quality achievable in this new medium is demonstrated for HSQC spectra leading to the conformational analysis of staurosporine and homonuclear TOCSY-type experiments.

TU München
Helmholtz München
MPI of Neurobiology
MPI of Biochemistry